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Bob is correct about the effects of barrier coating the exhaust.
In addition to what Bob said, there are two levels of thermal barrier coating, or what is referred to as 'ceramic' coating. While the coatings do have some ceramic components, it isn't really a ceramic at all. If it were, it would crack and fall off the first time the header got hot. The levels are low temp and hi temp. The low temp is what normally goes on NA engine headers. That can flake if overheated. The hi temp stuff is normally used for turbo exhaust as it gets much hotter than normal exhausts do. I have yet to see that suffer from over heating but I haven't seen it in the cool looking colors available for the low temp, only flat black.
There are also thermal dispersant coatings that shed heat, and maybe that is what you heard about. These are not normally applied to exhaust systems, but to radiators, intercoolers, and intakes, etc.
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Bob Raby
Santa Cruz, CA
'88 Alltrac (broken) FOR SALE
'87 4x4 Toy Truck SOLD
'90 4Runner (3.4 swap, CA certified legal with K&N intake, modified thermal coated headers, 2.5" exhaust, and almost as fast as a stock 3rd gen  ) SOLD
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