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For the tips...
If the tips are chrome, use a chrome polish (avoid a harsh metal polish unless it says it's safe for chrome).
If the tips are stainless steel, use a mag & aluminum or billet polish.
If it's soot build-up, you could also try a wheel cleaner that's safe for the finish -- just apply it carefully with an applicator so you don't get it in the exhaust pipe or anyplace you don't want it and can't rinse it away. Then polish.
For the tar on paint...
If they're big spots, before I'd try claying, I'd try mineral spirits or WD-40 (as PB suggested) or Goo Gone -- you might try saturating it over a period of a few minutes by repeated applications, or possibly soaking a piece of paper towel so it sticks to the affected panel. Then wash, clay and wax.
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1994 Camry V6 XLE - Cashmere Beige
2002 Sequoia - White
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