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Some alternative refrigerant blends contain hydrocarbons. I would not recommend them.
A retrofit from R12 is a compromise, at best. New R134A systems have the hoses, desiccant, seals, pressure switches and properly sized evaporators and condensers to make the best use of 134A's different vapor pressure.
As a "transitional" refrigerant, R134A is intended to bridge a gap between the nearly perfect mobile refrigerant R12 and whatever can be created that is as good as R12 but which is not perceived as detrimental to the environment.
Although the laws are already passed regarding the demise of R12 and the "facts" of its environmental action are being taught as a requirement for licensing, there is some discussion regarding the veracity of the arguments about R12 and the ozone layer. For example, no one seems bothered by chlorine atoms evaporating from the world's swimming pools and having a similar impact on the environment. If it is the chlorine in chlorofluorocarbons that is the problem, then we have a lot of pools to drain. But, I digress.
The best retrofit includes draining or flushing of old refrigerant oils, replacement of seals, hoses, and dryers (accumulators in some cars instead of dryers) and the addition of electric fans on cars and trucks with mechanically driven fans. A best case scenario would also include replacement of pressure switches with units calibrated for use with the pressures associates with R134A, which are higher than those of R12.
Many simple kits are sold to convert to R134A, and they should only be purchased BY the "simple." Can you get cool air from using a drop-in kit? Sure. How long it will function well, and how cold it can get are the two major issues. A hose, some oil, and a can or two of refrigerant will not be a good as a properly done conversion, called a "retrofit," and nothing in an R12 designed system will ever be as good as a full charge of R12.
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Courage...Honor...Conquer
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