Pulled the Cat off and it actually looked pretty good.
PB Blaster and a 6 point socket got it right off, pleasantly surprised and no busted knuckles!
No major clogging and the color was uniform.
With that said, I know my engine has been running rich due to bad fuel injectors. I'm not sure what a "poisoned" Cat looks like but since I had it off I decided to perform some preventative maintenance anyway. Not sure that's the wisest decision but I need this thing to breathe and wanted to eliminate the possibility of any problem there.
(Caution wear a dust mask when doing this, that's some very, very fine, cancer causing dust that will cloud up if you do this)
Tried the car after and no major difference as far as I can tell so I probably got rid of a perfectly good cat ... oh well, at least now I know it will never be a problem.

It does sound slightly different so I know it must have some effect.