If it is the TVV valve, it connects the canister with the P (purge) port throttle in your throttle. When the car is cold and the coolant tem is less than 39 C then that valve should be closed. This is very easy to check, just disconnect the hose of th P port and create a bit of vacuum. If air is passing when the car is cold the the valve is not working. On the other hand if you warm up the car and you create vacuum is normal to be able to get air flow, because the valve opens at approx 55 C. But, you should no be able to push any air into the cannister. I would carefully check the cannister.
Check this site
http://www.autoshop101.com/ look for the emisiion control article.