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1-replace the cabin filter if it is dirty, and it probably is.
2-if the relay is bad, then replace it. No you don't need to disconnect the battery.
3-any good a/c guy with test equipment can find a leak. Take it to an a/c repair shop to find and replace the leaky part. Might be simple like an o-ring or schraeder valve, or it could be the evaporator in which case 700 bucks will sound cheap.
4-your car does not use Freon unless it was manufactured before about 1994. It uses R134a, and that is not Freon.
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2007 V6 Camry LE, Built TMMK 27 September 06
"People who think they know it all are particularly irritating to those of us who do."
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