All car accessories (except AC) are run by the 12v battery, which is topped off by a step down converter (14.4v) running off the hybrid NiMH battery.
The more power accessories draw, the faster the hybrid battery depletes, which means less power for assist. The end result is reduced MPG. A high power device like the AC draws a lot of power, which makes a noticeable difference in MPG.
Adding LED DRLs won't make a noticeable short-term difference in MPG (unless you add up the savings over moths and years), but will look very cool.

I swapped all of my interior lights for LEDs and love the look. As a bonus, my wife left an interior light on once for 2 whole days, and the 12v battery was fine. LEDs typically draw less than 1/6th the power of halogens for equal light output.
To summarize, alternator power does not come free. On a normal car, putting a load on the alternator will put more drag on the engine, even while cruising on the highway. On an older car, while idling (to make it more noticeable), turn on all PURE electrical accessories (blower fans, high beams, stereo, rear defrost, etc) and watch the RPM's drop from the strain. You may even get belt squeal from the load if the belt is old.