In order to run the two sets of speakers off one amp it will need to be a 4-channel. To run them effectively you'll want an amp that pumps out about 100w RMS
per channel, so start looking for an amp that has a rating of around 600-800w max. Just be very wary of RMS rating and try and stick to well known brands.
Bear in mind that the rear speakers are only meant to be there to fill in the sound. Powering them through the amp may cause them to have too much treble and will through off the sound balance. I've experienced this personally and in order to fix it I had to fade the power from the amp more towards the front speakers via the head-unit, which defeats the purpose of buying high quality speakers for the rear since they'd only be running at quarter efficiency.
To get around this however, you can either buy cheaper, lower wattage speakers for the rear, or turn on the low pass filter on the amp for the rear speakers only (if the amp you buy has that selection). This will cancel out all of the high tones that your front speakers will already be producing, and won't make the rear speakers too 'hissy' and overpowered in terms of treble.
It takes a bit of trial and error to get the sound you're truly after. Everybody has different perceptions of what a good set-up should sound like, so have a play around with the settings on the head-unit and amp after you install it all. Have fun