You can look into those LDO or switching regulators from
Linear Technology or
Maxim IC. For a 20-W 5V output, you'll need something that can output 4-A. Typically, if you follow the guidelines for using the appropriate capacitor and inductor parts, you'll get a steady output. For a 4-A output, those passive parts will be pretty big, typically, you want to allow some headroom. You can find something that has a dual output with a single input. For a switching regulator, do pay attention to the switching frequency because that may cause the output to fluctuate, thus, those passives must be used properly. FYI, a PC will need a 3.3V and -5V output as well for the ATX specification. So it isn't easy (or cheap) as it may seem.