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Pressures should be measured with manifold gauges A/C in recirc mode, engine at 2000 RPMs, max cooling.
Low-side should be between 0.15-0.25 MPa (21-36 PSI)
High-side should be between 1.37-1.55 MPa (199-225 PSI)
Most people do not have this equipment to handle this sort of diagnosing/job. I would take it to a HVAC specialist. If the refrigerant level is low - then can recharge it correctly. If the level is too high, they can evacuate the system legally.
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2002 Corolla S, 1.8L 1ZZ-FE VVT-i
2003 Matrix XRS, 1.8L 2ZZ-GE, VVTL-i (RIP)
2009 Matrix XRS, 2.4L 2AZ-FE VVT-i
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