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Suggest doing a complete engine flush if changing coolants.
I use Zerex G0-5 that is somewhat cheaper and distilled water.
Toyota brand is not that much more expensive if you only do a change every 2 years.
The Toyota brand has no silicates or borates, if looking for an after market coolant look for these points.
As to the coolant in the over flow tank, this happens if fluid gets too old. Perhaps the flush was not complete, the tank can build up a lot of gunk over time on the bottom, the hose between the tank and radiator can start breaking down inside resulting in a black material inside the tank.
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