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Usually, speaking from my experience, white smoke means that there is coolant entering the combustion chambers. If you had issues with valve stem seals leaking the smoke would be a blue color from oil burning. My uncle had a 99 Camry with the same 3.0L eng as your Avalon and his was smoking on start up, but he had blue smoke. It was oil being burned, in his case he had sludge issues which clogged up the heads and forced oil past the valve seals into the combustion chambers.
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2005 Corolla LE - Impulse Red - Auto Trans - 1ZZFE - 86,000mi
2003 Echo - Auto Trans - 96,000mi. - slow as dog-dirt - I'd rather put my money in the bank than in the tank!!!!!
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