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It definitely sounds like a HG problem. A short burn like that, would not be noticeable in the coolant level. The fact that it started and stopped, while highway driving is a bit strange. It is possible that the leak sealed itself, temporarily. I would check the oil and coolant for signs of cross contamination. It wouldn't hurt to pull the spark plugs, to see if any of them appear to be wet or cleaner than the others. The next start, after a prolonged sit, should let you know if a leak still exists. The white smoke plume will be there at start up.
If there are no signs found, it wouldn't hurt to add a can of stop leak, just to be safe.
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