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High NOx levels are a sign of too high of a combustion temperature - car is running too lean, not enough fuel to help cool down the resulting mix. Could be too much advance on timing, hot spots in engine, vacuum leaks.
The suggestion for high octane is a pretty decent test. High octane resists detonation, which could be generated by hots spots in the engine, or excessive combustion deposits that are effectively raising your compression ratios.
Do you have more information on the test - was the high NOx on acceleration, idle, etc.?
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2002 Corolla S, 1.8L 1ZZ-FE VVT-i
2003 Matrix XRS, 1.8L 2ZZ-GE, VVTL-i (RIP)
2009 Matrix XRS, 2.4L 2AZ-FE VVT-i
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