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If you are talking about gasoline grades, it's said that regular burns sooner/easier than super, so much that in FI or high compression engines regular gas would start burning before it's intended to, aka detonation.
What he may be seeing is less ethanol in super gas than regular gas - that is said to drop your gas mileage by 2 mpg or so. People on cleanmpg sometimes go to great lengths to find pure gas, but I recently ran a tank of Shell V-Power (it's "supreme" gas) which claims to be ethanol free, and I fail to see a difference.
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