I'd guess a blend door is not working. Blend doors determine whether hot or cold air comes out the vent. They are under the dash.
In some cars blend doors are powered by little electric motors, and in some vacuum. I think Toyotas use the motors, which are also called actuators.
There is a rod between the actuator and the blend door.
Some possibilities:
Rod came loose.
Actuator motor failed.
Blend door is jammed.
Here's a thread on an older Camry, with some good illustrations:
2000Camry broken blend door
Here's a thread on 4-runner's, with a problem like yours:
http://www.toyota-4runner.org/4th-ge...vers-side.html