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I'm not sure anyone can help without actually being there but more information would sure be helpful
What year Solara do you have
four cylinder or six
stick shift or automatic
by "doesn't accel" do you mean it just sits with the transmission in gear and won't move (one extreme) or the car is just more sluggish than it used to be?
By "doesn't accel" when cold do you mean it's fine once the engine is up to normal operating temperature but then "won't accel" again when you turn on the AC? Turning off the AC everything is normal again?
Is your check engine light on or has it come on at all?
I guess you can see how having all the facts would at least allow forum members to make a 'guess' at your problem.
If I were to take a guess based on your information, especially taking the mileage into account, I'd guess your spark plugs are in need of changing. Now, if you have the 6 cylinder and you did that as scheduled around 100,000 with Iridium plugs then you can toss that guess immediately.
If you were low on power all the time I'd hazard a guess the fuel filter may be clogged but if it's only cold and only when AC is running then that one doesn't fly either.
The same applies to the catalytic converter. All the time low power then it could be clogged. Only under certain conditions, probably not.
If your problem was a 'sudden onset' sort of thing then you should try to figure out what was done differently when the symptom showed up. Different fuel?
The curious thing is the 'only when cold' and 'only when AC is on' symptom that you suggest. I can't figure out how the two might be linked.
I realise this hasn't been the least bit helpful but if you'll repost with more facts maybe something will occur to someone.
Cheers
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