Maybe I'm misunderstanding what you mean by the "EV-only" part but I think that the system can use this extra battery charge garnered by the PED to also help power the Highlander by supplementing the gas engine use thus reducing load on the gas engine and improving fuel efficiency - not just in electric only mode. Possibly could be done either before a long downhill stretch to help make room for the upcoming charge or after the long downhill stretch depending on up coming terrain.
I already have a number of these deceleration green icons on my map where I always use the brakes around town.