4th generation Highlander seems to have a faulty freon line to the rear condenser that needs to be a Toyota recall.
My 2020 line failed "due to corrosion" at 16,000 miles. There are only a few points of light surface rust on some of the other body hardware under the splash panels, no significant corrosion on any other lines.
Another thread here reported the same and that even Toyota was out of stock on the lines (due to demand?).
Dealer repair cost was $703 for line replacement & recharge.