no. if there is any difference totally negligible. Same as the old days when there was Ethyl, and Super (pre 1985 in the USA, actually mostly for the cars before than but that is about when the USA did the drastic no-lead change). if you had a car requiring super, it would run horrible and damage an engine that required it. But, if you had low performing Pinto, or older 38 HP VW, adding the 100 octane did nothing but waste money. There were actual instances of people damaging their plugs and engines from running the very high octane in some cars and bikes. Also, Europe was 10 years behind in the conversion from leaded gas to non-leaded because they had higher performance engines for faster running cars and roads like in Germany. It was usually the compression ratio that determined the level of lead, before the formulas in fuel changed to for most engines accepted no lead, or low lead. The materials and engines changed to allow new formulas to run without the bad effects on engines. The lead helped slow the pre-ignition, where the infamous engine rattle came from with the wrong octane. The ignition came long before tdc of the piston and also there are hot spots in the cylinder that would pre-ignite the fuel. There are instances where the conditions driven might benefits for the slight boost in octane. Say from 87 to 89. Or 89 to 92. But, if the car says 89, then use 89. If that leaves questions, then if your engine and car is a sporty version with the turbo, or higher performance engine, non standard but an option with performance increase, or higher than 9:1 compression than it is safe to assume it will need a bump up in octane. if the engine rattles when accelerating, or a has after run after turning off than it might need the next octane up. It is much easier to just go with the what manufacturer says. If you have a performance car, you will know it without question. There are cases of some fuel at some gas stations may be of better quality, Top Tier gas. That can also be of benefit in choosing your car's gas to use. IMHO