32 to 35psi is not going to be significant impact on fuel economy. It will have SOME impact, but not a lot... 32 is low, but totally acceptable.
Sitting with the system "idling" listening to the stereo can be a killer, particularly if you are doing primarily short trips. While hybrid tech benefits from "stop and go" driving to a degree (my Avalon gets close to 50 on Los Angeles freeways), if these are short trips, the ICE will run until the system is up to operating temperature.
Don't be tempted to shut the system down and listen to the stereo without the hybrid system in the full "Ready" mode... the 12v battery is much smaller than a conventional vehicle and you can kill it quickly (look for Luddite's recent post about killing his battery, though he's never been clear that he has a hybrid)
Running the AC is more efficient than driving with the windows down once you're above 25-30mph, but it's really not a significant impact either way. These aren't the old R12 systems that you could really feel when you turned them on even with a 300hp Chevy 350.
As far as I can tell, "Tank" resets when the system senses the tank has been refilled... I've not tried just popping my fuel door to see if it resets.
Total is the average MPG between when you reset the total. On mine it's when I tap "update" on the stereo's Eco screen. The 199.9 on this is because I took the shot while waiting in line at the car wash, and the system had remained in EV mode from the gas pump to the car wash.
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