Just to clarify, R134 is not the same as R134
a. While both are tetrafluoroethane, they are isomers with slightly different physical arrangements:
R134 is CHF2-CHF2 symmetical 1,1,2,2-tetrafluoroethane
R134a is CF3-CH2F and arranged as 1,1,1,2-tetrafluoroethane
R134 originally was used as a replacement for R12 freon, but was found to be not as effiicent. R134a was its successor and ends up being more efficient than R12, thus the lower amounts needed in retro-fitted AC systems.
R134a's not exactly benign however, it's on the list of greenhouse-gases and has been banned in the EU since 2011. The SAE has proposed HFO-1234yf CF3CF=CH2 as its replacement. It's unfortunate due to its fairly inert chemical nature, that it's not a more controlled substance. R134a has been implicated in numerous teenage "huffing" and "dusting" deaths:
Snopes.com - Dusted Off. Then again, asphyxiation and death can also occur from CO2, N2, propane, pillows, plastic-bags, etc. anything that prevents O2 in the air from getting into your lungs (doesn't even have to chemically react with anything).
BTW - I've used propane from my BBQ tank as a refrigerant in cars and it actually works! But I would be worried about leaks and potential fires, so no converting my engine into a BBQ allowed!